Roya Maboudian (Advisor)

Metal-organic frameworks (MOFs) are porous, high surface area materials that consist of metal-cluster nodes connected by organic linkers to form highly ordered structures with various pore geometries and chemical properties. Due to their unique and tunable structure, MOFs have shown substantial promise in a broad range of applications, including chemical sensing, gas adsorption and separation, and catalysis. To investigate the intrinsic properties of MOFs for their sensing performance, single crystals are ideal platforms that mitigate the impact of defects, impurities, and grain...

Chemiresistive gas sensors based on semiconductor metal oxides, such as tin oxide (SnO₂), play a critical role in detecting toxic gases and monitoring pollution in industrial and environmental applications. Siloxanes, organic compounds that contain silicon and oxygen atoms and are widely used in personal care products, are commonly present in various environments. The presence of these compounds can significantly degrade sensor performance by modifying the oxide surface, altering its gas adsorption properties, and reducing both sensitivity and selectivity in gas sensing. To address this...

Hydrogen safety demands highly sensitive H2 sensors with rapid response (< 30 s) to detect leakage at concentrations far below its explosion limit (40,000 ppm). Nanostructured materials based on palladium (Pd) and its alloys emerged as the most promising candidates that meet the standards set by the U.S. Department of Energy for hydrogen sensors. In this study, we are developing novel robust chemiresistive gas sensors employing single-crystalline mesoporous bimetallic alloys (s-meso PdM) nanocubes (NCs) on ordered mesoporous tin (IV) oxide (m-SnO2) for remote and distributed H2 sensors...